准格尔煤田黑岱沟露天矿煤中稀土及微量元素的分配规律     

刘大锐  高桂梅  池君洲  王永旺  郭昭华 《地质学报》2018,92(11):2368-2375

对准格尔煤田黑岱沟露天矿煤的主量元素、稀土元素和微量元素含量和矿物组成进行了研究。结果表明,黑岱沟露天矿煤中稀土元素平均含量为248.12×10-6,约为中国煤平均值的2.83倍。LREE平均含量为236.66×10-6,HREE平均含量为11.46×10-6,LREE/HREE平均值为20.81,(La/Yb)N平均值为1.59,表明煤中LREE相对HREE富集。煤中部分稀土元素可能富集在勃姆石和黏土矿物中。稀土元素分配曲线δCeS变化区间(0.89～2.21)和δEuS中度亏损(0.46～0.86),验证了沉积环境在煤层形成演化过程中对煤中稀土元素输入的稳定性。黑岱沟煤层中微量元素明显偏高的有Ga、Pb、Se、Sr、Th 和Zr,这些元素的含量高于中国、中国华北晚古生代和美国煤的算术均值,也高于地壳克拉克值。  相似文献   

Jurassic and Cretaceous (Yanshannian) tectonics,magmatism and metallogenesis in South China: preface     

Xiaoyong Yang  Weidong Sun 《International Geology Review》2018,60(11-14):1321-1325

ABSTRACT

South China is famous for its poly-metal deposits, with more than 50% of global W and Sb reserves, 20% of global Sn reserves, as well as abundant Cu-Mo-Pb-Zn-Au-Ag, Ta, Nb, REE and U deposits. This special issue consists of 21 papers, reporting recent progress on Yanshannian tectonic evolution, magmatism and ore deposits in South China, aiming at better understandings on the Mesozoic large-scale magmatism and mineralization events.  相似文献   

3D打印技术在矿床学中的应用研究——以内蒙古乌力吉敖包萤石矿Ⅲ号矿体为例     

陈奇 《地质与勘探》2018,54(4):833-845

3D打印(3D printing)是一种以三维模型为样本的快速成形技术,它通过逐层打印或粉末熔铸的方式来构造需要的立体图形。本文从3D打印技术的原理及其发展现状入手,重点列举内蒙古乌力吉敖包萤石矿,利用3D打印机打印具有现实可观性的地质体实体,探讨3D打印技术作为新兴的科技手段应用于矿床学教学与研究的应用价值和发展前景。研究发现,3D打印技术在矿体三维可视化中的应用符合地质图件立体化和3D打印技术多领域化的趋势,未来3D打印技术在地质领域的应用也有助于开拓矿床学教学和研究的新方式与新思路。  相似文献   

天山-兴蒙造山带主要钼矿床Re-Os定年和地质意义          下载免费PDF全文

郭瑞清柴凤梅  韩春明 《地质科学》2018,(3):1119-1135

天山-兴蒙钼矿带是中亚成矿域的重要组成部分,该成矿带主要呈近东西向分布;本文通过对天山-兴蒙钼矿带4个典型矿床Re-Os同位素精确定年,结合前人区域动力学背景的研究,揭示天山-兴蒙造山带钼矿床的成矿作用主要与岩浆侵入形成的花岗岩热液作用有关,并识别出兴蒙造山带3期岩浆活动、钼成矿作用和构造热事件;Re-Os定年结果揭示出晚古生代铜-钼矿床与俯冲-增生作用有关,三叠纪钼的成矿形成于西伯利亚板块与塔里木-华北克拉通碰撞背景下,而侏罗纪-早白垩世的钼成矿作用与古太平洋板块西向俯冲作用有关。  相似文献   

斑岩型钼矿床研究进展与问题   总被引：1，自引：0，他引：1  

曹冲  申萍 《地质论评》2018,64(2):477-497

本文在简要介绍全球重要成矿带斑岩型钼矿床品位、储量、时空分布以及构造背景的基础上,着重归纳了斑岩型钼矿床中Mo在岩浆—热液演化过程中的地球化学行为特征以及Mo在成矿流体中的迁移与沉淀机制两个方面的研究进展。取得了以下认识:形成斑岩型钼矿床成矿岩浆氧逸度(f_(O2))变化范围较大,但一般大于铁橄榄石—磁铁矿—石英(FMQ)缓冲体系。斑岩钼矿床形成的主要受岩浆房的大小,大体积的岩浆流体能否高效聚集到浅部岩株或岩脉,岩浆中的挥发分(例如F)含量等因素的控制,但与成矿花岗岩和出溶流体中Mo的含量高低无直接关系。成矿流体的氧逸度与p H降低对辉钼矿沉淀具有关键作用。除此之外,温度与盐度降低对辉钼矿沉淀也有重要作用。流体的多阶段沸腾可能对提高Mo品位具有重要意义。此外,应加强岩浆结晶分异过程、岩浆热液转化过程Mo的地球化学行为研究。  相似文献   

哈萨克斯坦楚—萨雷苏盆地砂岩型铀矿床地质—伊犁盆地蒙其古尔铀矿床含矿砂岩成岩蚀变特征及其有机-无机流体成岩成矿效应     

丁波  刘红旭  李平  张虎军  张宾  潘澄雨  张晓 《地质论评》2018,64(1):149-164

伊犁盆地蒙其古尔铀矿床为典型的层间氧化带型铀矿床,虽然前人对该区铀矿的成矿流体进行了较为系统的研究,但对其成矿流体来源依然存在较大的分歧,尤其对该区成矿流体与蚀变特征、铀成矿的内在联系研究较少。本文为了研究蒙其古尔铀矿床成矿流体来源及其与成岩蚀变、铀成矿的内在联系,综合地应用了偏光显微镜、扫描电镜、电子探针等手段,对其含矿目的层砂岩成岩蚀变进行系统的分析,并对蚀变矿物高岭石H—O同位素、碳酸盐胶结物C—O同位素及黄铁矿S同位素进行了研究。研究表明：与砂岩型铀矿有关的成岩蚀变类型主要有黏土化、碳酸盐化、硅化及金属矿化;成矿流体中水δDH2O,V SMOW为-48.3‰～-93‰, δ18OH2O,V SMOW为-10.3‰～-5.1‰,碳酸盐胶结物δ13CV PDB为-10.9‰～-7.2‰,δ18OV SMOW为176‰～249‰,黄铁矿δ34SV CDT为-17.3‰～12‰,上述特征揭示蒙其古尔铀矿床成矿流体是由大气降水性质的地表水（无机）和煤系地层有机质脱羟基及热降解作用产生的有机酸及CH4等还原性气体（煤层气）（有机）两部分组成;成岩蚀变和铀成矿效应皆是有机—无机流体及流体与周围砂岩相互作用的结果。  相似文献   

微波消解-电感耦合等离子体质谱法测定海泡石中的稀土元素   总被引：3，自引：3，他引：0  

张楠  徐铁民  吴良英  魏双  方蓬达  王家松 《岩矿测试》2018,37(6):644-649

海泡石是一种纤维状含水的富镁硅酸盐黏土矿,其中的稀土元素含量在1×10~(-7)～1×10~(-5)之间,目前还没有建立海泡石中稀土元素的国家标准分析方法。测定岩石中的稀土元素主要是采用电感耦合等离子体质谱法(ICP-MS),样品前处理一般采用封闭溶矿和碱熔,但这两种处理方法耗时较长,效率不高。本文通过比较硝酸-氢氟酸-过氧化氢、硝酸-氢氟酸、硝酸-过氧化氢三种样品前处理方法,确定使用硝酸-氢氟酸溶矿,然后进行微波消解同时赶去氢氟酸,避免氢氟酸与稀土元素生成难溶的氟化物,再采用ICP-MS法测定15种稀土元素的含量。由于海泡石中的镁含量较高,为降低基体效应,以~(103)Rh和~(185)Re作内标补偿基体效应和校正灵敏度漂移,各元素测定值的准确性显著提高,回收率为91. 2%～110. 9%,检出限为0. 002～0. 011μg/L,精密度≤2. 79%。本方法与封闭酸溶ICP-MS法的分析结果吻合较好,且用酸量少(7 mL),溶矿效率高(1 h),检出限更低。  相似文献   

The source of sulfur in sulfide deposits in the Siberian Platform traps (from isotope data)     

V.V. Ryabov  O.N. Simonov  S.G. Snisar  A.A. Borovikov 《Russian Geology and Geophysics》2018,59(8):945-961

The source of sulfur in giant Norilsk-type sulfide deposits is discussed. A review of the state of the problem and a critical analysis of existing hypotheses are made. The distribution of δ³⁴S in sulfides of ore occurrences and small and large deposits and in normal sedimentary, metamorphogenic, and hypogene sulfates is considered. A large number of new δ³⁴S data for sulfides and sulfates in various deposits, volcanic and terrigenous rocks, coals, graphites, and metasomatites are presented. The main attention is focused on the objects of the Norilsk and Kureika ore districts. The δ³⁴S value varies from -14 to + 22.5‰ in sulfides of rocks and ores and from 15.3 to 33‰ in anhydrites. In sulfide-sulfate intergrowths and assemblages, δ³⁴S is within 4.2-14.6‰ in sulfides and within 15.3-21.3‰ in anhydrites. The most isotopically heavy sulfur was found in pyrrhotite veins in basalts (δ³⁴S = 21.6‰), in sulfate veins cutting dolomites (δ³⁴S = 33‰), and in subsidence caldera sulfates in basalts (δ³⁴S = 23.2-25.2‰). Sulfide ores of the Tsentral’naya Shilki intrusion have a heavy sulfur isotope composition (δ³⁴S = + 17.7‰ (n = 15)). Thermobarogeochemical studies of anhydrites have revealed inclusions of different types with homogenization temperatures ranging from 685 °C to 80 °C. Metamorphogenic and hypogene anhydrites are associated with a carbonaceous substance, and hypogene anhydrites have inclusions of chloride-containing salt melts. We assume that sulfur in the trap sulfide deposits was introduced with sulfates of sedimentary rocks (δ³⁴S = 22-24‰). No assimilation of sulfates by basaltic melt took place. The sedimentary anhydrites were “steamed” by hydrocarbons, which led to sulfate reduction and δ³⁴S fractionation. As a result, isotopically light sulfur accumulated in sulfides and hydrogen sulfide, isotopically heavy sulfur was removed by aqueous calcium sulfate solution, and “residual” metamorphogenic anhydrite acquired a lighter sulfur isotope composition as compared with the sedimentary one. The wide variations in δ³⁴S in sulfides and sulfates are due to changes in the physicochemical parameters of the ore-forming system (first of all, temperature and P_ch4) during the sulfate reduction. The regional hydrocarbon resources were sufficient for large-scale ore formation.  相似文献   

Geodynamic setting,structure, and composition of continuous trachybasalt-trachyandesite-rhyolite series in the north of Altai-Sayan area: the role of crust-mantle interaction in continental magma formation     

A.A. Vorontsov  O.Yu. Perfilova  N.N. Kruk 《Russian Geology and Geophysics》2018,59(12):1640-1659

The geologic positions and geochemical and isotope parameters of the Ordovician-early Silurian and Early-Middle Devonian continuous volcanic series of the Minusa basin and its mountainous framing are compared. Both series are composed mostly of moderately alkaline rocks with variations in SiO₂ contents from 45 to 77 wt.%. The Ordovician-early Silurian series differs from the Early-Middle Devonian one in lower contents of TiO₂ (< 1.7 wt.%) and Fe₂O_3tot and higher contents of Al₂O₃ in all rock varieties and in the more fractionated REE patterns of trachybasalts. The compositions of both series reflect two simultaneous mechanisms of magma evolution. The main process was fractional crystallization leading to the formation of rocks from trachybasalts to trachyrhyodacites. The accessory mechanism was the contamination of fractionated melts by crustal material, anatectic melting of crust, and mixing of deep-seated magmas with crustal melts. These processes had specifics at each stage and were controlled by the composition of the sources of parental melts. Their geochemical and isotopic parameters (high alkalinity, high contents of lithophile elements, negative anomalies of Nb, Ta, and Ti, and enrichment in radiogenic Sr) point to the interaction of mantle plumes with the lithospheric mantle that was metasomatically transformed during the preceding Vendian-early Cambrian subduction processes.  相似文献   

Exhumation of the Mesozoic Guojialing Granodiorite: Implication for the Preservation of Gold Deposits in the Jiaobei Terrane,China     

《Resource Geology》2018,68(1):51-64

Preservation conditions are very important for mineral systems and a suitable exhumation process is critical for endogenetic deposits, especially for those deposits formed in orogenic settings, where deposits are inclined to erode away due to strong uplift. The G uojialing batholith, intruding into the L inglong granites and the J iaodong G roup right before regional gold mineralization, is one of the most important gold ore‐hosting M esozoic intrusions in the J iaobei terrane. Gold deposits and the intrusion together underwent similar tectonothermal evolutionary processes. Exhumation and denudation process of the G uojialing granodiorite was constrained by biotite geobarometry and apatite fission track (FT ) analysis. Biotite geobarometric data yields an emplacement depth of 3.0 km, while denudation since 110 M a was calculated from the FT data at about 2.7 km. FT inverse modeling revealed a rapid uplift since ca 100 Ma. Compared with the gold ore‐forming depth which is confined between 2.5 and 9.5 km by fluid inclusion studies, great gold potential in the depths is inferred in the J iaobei terrane. Our result is consistent, to some extent, with the hypothesis of a M esozoic paleoplateau in E ast C hina.  相似文献